Search results for " Multi-layered ionic liquids"

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Palladium supported on Halloysite-triazolium salts as catalyst for ligand free Suzuki cross-coupling in water under microwave irradiation

2015

Abstract Environmental friendly halloysite-dicationic triazolium salts (second generation) obtained by subsequent click reactions of a diyne derivative in the presence of 2-azidopropyl-modified halloysite nanotubes, were used as supports for palladium catalyst. Thanks to the high triazolium loading (25%) these materials were able to support higher amount of the metal than that on the monocationic derivative (first generation). Such materials were characterized by thermogravimetric analysis, FT-IR spectroscopy and SEM investigations. The new catalytic system was employed in the ligand free Suzuki cross-coupling under microwave irradiation. A set of solvent, time and% loading of palladium was…

Thermogravimetric analysisSuzuki reactionHalloysite nanotubeInorganic chemistrychemistry.chemical_elementengineering.materialTriazolium saltHalloysiteCatalysisCatalysisMetalchemistry.chemical_compoundMulti-layered ionic liquidTriazolium salt Multi-layered ionic liquids Halloysite nanotubes Suzuki reaction MicrowavePhysical and Theoretical ChemistrySettore CHIM/02 - Chimica FisicaBiphenylProcess Chemistry and TechnologySettore CHIM/06 - Chimica OrganicaSolventchemistryvisual_artvisual_art.visual_art_mediumengineeringLeaching (metallurgy)MicrowavePalladiumJournal of Molecular Catalysis A: Chemical

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